Preparation of Ni/Bentonite Acid-Activated using Dragon Fruit Peel Extract (Hylocereus polyrhizus) As a Reductor for One Pot Synthesis of Menthol

Yuni Marhayuni, Priyagung Dhemi Widiakongko

Abstract


Ni/Bentonite is acid-activated has been synthesized using dragon fruit peel extract (Hylocereus polyrhizus) as a reductor through an impregnation method. This research aims to characterize Ni/Bentonite acid-activated using dragon fruit peel extract as a reductor based on FTIR and XRD instruments and to analyze the product obtained in one pot synthesis of menthol from citronellal using Ni/Bentonite acid-activated catalyst. Preparation of Ni/Bentonite acid-activated catalyst was carried out using a wet impregnation method with dragon fruit peel extract as a natural reductor. The successful synthesis of Ni/Bentonite acid-activated was confirmed by FTIR spectrum identification, showing absorptions at wavelengths of 1049.28 cm?¹ and 694.37 cm?¹, indicating Si-O groups in the bentonite, and XRD diffractogram indicating the presence of Ni at diffraction peaks of 2? = 40.5° and 2? = 47.74°. The catalyst was able to convert menthol by 0.77% through one pot synthesis without using H? sources such as potassium formate.

Keywords


dragon fruit peel extract; impregnation; menthol; Ni/Bentonite; one pot synthesis

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DOI: https://doi.org/10.14421/biomedich.2024.132.523-530

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Copyright (c) 2024 Yuni Marhayuni, Priyagung Dhemi Widiakongko



Biology, Medicine, & Natural Product Chemistry
ISSN 2089-6514 (paper) - ISSN 2540-9328 (online)
Published by Sunan Kalijaga State Islamic University & Society for Indonesian Biodiversity.

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